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1.
Dealloyed nanoporous gold (np-Au) has applications as oxygen reduction catalysis in Li-air batteries and fuel cells, or as actuators to convert electricity into mechanical energy. However, it faces the challenges of coarsening-induced structure instability, mechanical weakness due to low relative densities, and slow dealloying rates. Here, monolithic np-Au is dealloyed from a single-phase Au25Ni75 solid-solution at a one-order faster dealloying rate, ultra-low residual Ni content, and importantly, one-third more relative density than np-Au dealloyed from conventional Au25Ag75. The small atomic radius and low dealloying potential of the sacrificing element Ni are intrinsically beneficial to fast produce high relative density np-Au, as predicted by a general model for dealloying of binary alloys and validated by experiments. Stable, durable, and reversible actuation of np-Au takes place under cyclic potential triggering in alkaline and acidic electrolytes with negligible coarsening-induced strain-shift. The thermal and mechanical robustness of bulk np-Au is confirmed by two-order slower ligament coarsening rates during annealing at 300 °C and 45 MPa macroscopic yielding strength distinctive from the typical early onset of plastic yielding. This article opens a rich direction to achieve high relative density np-Au which is essential for porous network connectivity, mechanical strength, and nanostructure robustness for electrochemical functionality. 相似文献
2.
近年来在下扬子地区页岩气地质调查井所获取的地层岩心资料,揭示该地区下志留统风暴沉积较为发育。基于精细的岩心观察描述,详细分析了下扬子地区下志留统高家边组下段中上部风暴沉积的特征,并阐明了风暴作用对泥页岩的影响。研究表明:研究区风暴岩岩性偏细,以粉砂岩为主,石英含量较高,结构成熟度较低,具2种不同的粒度概率曲线;主要发育底部冲刷面、块状层理、平行层理、丘状交错层理、波纹交错层理、准同生变形构造等沉积构造;垂向上主要识别出4种风暴沉积序列,均具有从底到顶粒度变细的沉积特征,不同的沉积序列与风暴流能量的强弱有关。下扬子地区早志留世频繁的风暴活动与研究区的古地理背景和古气候条件具有内在联系。特大型风暴对浅海陆棚深水区的细粒泥质沉积物特征产生重要影响,包括降低有机质含量、减少单层厚度、破坏垂向连续性、改变原始沉积构造和侧向稳定性等,总体上降低了泥页岩的品质。因此,研究认为在页岩气的勘探和评价过程中应重视风暴因素对陆棚深水区原始泥质沉积物的影响。 相似文献
3.
Stefano Mariani Antonino Amedeo La Mattina Alessandro Paghi Lucanos Strambini Giuseppe Barillaro 《Advanced functional materials》2021,31(26):2100774
Here, a fluoride-assisted route for the controlled in-situ synthesis of metal nanoparticles (NPs) (i.e., AgNPs, AuNPs) on polydimethylsiloxane (PDMS) is reported. The size and coverage of the NPs on the PDMS surface are modulated with time and over space during the synthetic process, leveraging the improved yield (10×) and faster kinetics (100×) of NP formation in the presence of F− ions, compared to fluoride-free approaches. This enables the maskless preparation of both linear and step gradients and patterns of NPs in 1D and 2D on the PDMS surface. As an application in flexible plasmonics/photonics, continuous and step-wise spatial modulations of the plasmonic features of PDMS slabs with 1D and 2D AgNP gradients on the surface are demonstrated. An excellent spatially resolved tuning of key optical parameters, namely, optical density from zero to 5 and extinction ratio up to 100 dB, is achieved with AgNP gradients prepared in AgF solution for 12 minutes; the performance are comparable to those of commercial dielectric/interference filters. When used as a rejection filter in optical fluorescence microscopy, the AgNP-PDMS slabs are able to reject the excitation laser at 405 nm and retain the green fluorescence of microbeads (100 µm) used as test cases. 相似文献
4.
《中国有色金属学会会刊》2021,31(9):2812-2822
To improve five-year survival rate of oral squamous cell carcinoma (OSCC), the development of a novel composite material of black phosphorus nanosheets (BPNSs) and gold nanoparticles (AuNPs) for tumor treatment was carried out. The purpose of this study is to evaluate the cytostatic effects of BPNSs, AuNPs loaded with cisplatin (CDDP) on human tongue squamous cell carcinoma cells lines (SCC-9), and 7,12-dimethylbenz anthracene induced cheek squamous cell carcinoma was validated in golden hamsters animal models. The results showed that BPNSs could efficiently inhibit the metastasis and growth of OSCC compared with CDDP and AuNPs. And a combination composite of AuNPs–BPNSs loaded with CDDP could more effectively inhibit the metastasis and growth of OSCC, which might be due to the high drug-loading capacity, excellent photothermal properties and the combination of photodynamic and photothermal therapy of BPNSs and AuNPs, as well as the synergistic effects of AuNPs, BPNSs and CDDP. 相似文献
5.
Océane Florès Dr. Denis Velic Nesrine Mabrouk Prof. Ali Bettaïeb Christophe Tomasoni Prof. Jean-Michel Robert Dr. Catherine Paul Dr. Christine Goze Christos Roussakis Dr. Ewen Bodio 《Chembiochem : a European journal of chemical biology》2019,20(17):2255-2261
A family of bi- and tetrametallic gold(I) phosphine dithiocarbamate complexes were synthesized, starting from cyclam and dimethylcyclam polyazamacrocycles, respectively, along with their monometallic gold(I) chloridophosphine precursors. Their antiproliferative properties were evaluated on two cancer cell lines (A549 and NSCLC-N6-L16). Most of the mono- and bimetallic complexes displayed strong activities and, in particular, one bimetallic derivative showed antiproliferative properties in the low micromolar range. Insights into the structure–activity relationships are given, along with determination of the thioredoxin reductase inhibition potential, two-photon imaging of the fluorescent derivatives, and evaluation of gold uptake. 相似文献
6.
7.
干河坝金矿床是南秦岭南段勉略康构造混杂岩带内属受岩相和构造双重控制的构造蚀变岩型金矿床。该矿床的矿体集中产于古生界泥盆系金家河岩组金家河千枚岩与乔子沟火山岩的岩性—构造接触带附近,多呈似层状、透镜状。为进一步探讨该矿床成因,通过对矿床成矿地质特征、地球化学背景及硫同位素的系统研究,认为:①该矿床的赋矿层位就是其初始矿源层;②经区域变质变形和多期构造活动,初始矿源层中的成矿物质活化、迁移,在近EW向张性裂隙中充填、沉淀而富集成矿。 相似文献
8.
This paper presents two well-instrumented large-scale field tests of PVD-improved soft soil with vacuum and surcharge preloading, respectively. The two large-scale field tests were conducted adjacent to each other with the same preload. A comparative analysis was performed to investigate the performance of subsoil (i.e., the ground settlement, the layered settlement, the lateral displacement of subsoil and pore water pressure) under vacuum preloading and equivalent surcharge preloading. Some design methods were verified based on the field data. Cone Penetration Tests (CPT) and Vane Shear Tests (VST) were conducted to assess the improvement effects on subsoil after preloading. The results showed that as compared with surcharge preloading, vacuum preloading mitigated the differential settlement of the ground. The vacuum pressure transmitted into the soil with a minor loss through the PVD length. From a practical point of view, the improvement effects by vacuum preloading and surcharge preloading were similar in terms of influence depth and soil strength based on the in-situ tests. 相似文献
9.
湖南省郴州市饭垄堆北段锡钨多金属矿位于湘南钨锡钼铋多金属成矿带东坡矿田内,成矿地质条件优越,具有很好的找矿前景。根据该矿床地质特征以及已有的地质矿产勘查成果,系统总结了矿区101、102、103号主矿体特征。在此基础上,进一步讨论了该类裂隙充填细脉带型锡钨多金属矿床在勘查过程中探矿工程布置的优化方法:即:①探矿工程不宜按每个矿带单独控制,应对整个赋矿层位进行整体控制;②应对含有毒砂、锡、钨细脉的岩性段进行连续取样化验,既可避免漏矿,又可以为将来工业指标调整后重新圈定矿体提供直接依据。 相似文献
10.
通过对某矿床开采技术条件和矿体赋存特征分析研究,采用3DMine软件平台建立三维数字化矿体模型,确定上、下2个采区的最佳分界线标高为850 m,确定上部采区竖向开采范围为990~850 m,下部采区竖向开采范围为850~670 m。以矿床36号剖面勘探线为例,采用K.B.鲁别涅依他等人的公式对上、下采区间水平岩柱的临界厚度进行计算,得出上、下采区同时开采的安全间距为42 m。采用UDEC软件对矿床36号剖面水平岩柱稳定性进行数值模拟,水平岩柱在垂直方向上的最大位移为4.62 cm,对水平岩柱的整体稳定性没有影响。分区方案留设的水平岩柱可以保证上、下采区同时安全开采。 相似文献